Application of methyl MQ silicone resin in composite materials
Source:iotachem.com
PostTime:2025-08-10 23:39:24
Methyl MQ silicone resin is mainly used as a key component of mold release agent, reinforcing filler, and functional additive in composite materials. It significantly enhances the overall performance of composite materials by optimizing interface properties, improving mechanical strength, and imparting special functions. Its application value has covered many fields such as electronic packaging, high temperature protection, and precision manufacturing.The following analysis is carried out from three aspects: core mechanism of action, typical application scenarios, and performance breakthrough direction:
1. Core mechanism of action: interface regulation and performance enhancement
The molecular structure of methyl MQ silicone resin is formed by the polymerization of monofunctional methylsiloxane (M unit) and tetrafunctional siloxane (Q unit) to form a three-dimensional mesh structure. This unique design gives it dual functions.:
Chemical bonding and physical film formation: The hydroxyl groups of unit M can form hydrogen bonds or chemical bonds with the surface of the mold, while the methyl groups are arranged outward to form a low surface energy layer, forming a dense and flexible release interface film.
Reinforcement and toughening effect: In composite materials such as silicone rubber, MQ resin condenses with PDMS through hydroxyl groups to form a three-dimensional reinforcement network, which significantly improves the tensile strength (up to 12Mpa) and elongation at break (350%) of the material.
Functional modification: By introducing organic groups such as epoxy and chloromethyl, it can be extended to MDQ or MTQ structure, giving the material special properties such as viscosity, UV resistance, and radiation resistance.
2. Typical application scenarios: multi-field performance breakthroughs
Electronic packaging composite materials
LED packaging glue: As the base material, methyl MQ silicone resin provides high light transmittance (>98%), high temperature resistance (long-term use at 250℃) and anti-ultraviolet radiation properties to ensure the long-term stability of the packaging layer.
Semiconductor potting glue: The mechanical strength of silicone rubber is enhanced by reinforcement, and its low volatile content (<0.35%) characteristics meet the stringent requirements for cleanliness of electronic components.
High temperature protection composite material
H-class motor insulation coating: using its excellent heat resistance (>300℃) and electrical insulation properties, it is used as a film-forming agent for high-temperature coatings to protect motor windings from thermal damage.
Building sealant: In the sealing of building joints, the weather resistance and chemical resistance of MQ resin can significantly extend the sealing life and reduce maintenance costs.
Precision manufacturing mold release agent
Polyurethane release: By adjusting the M/Q ratio (0.6-1.0), the flexibility and strength of the release agent are optimized, so that the number of release times is increased to 8-12 times, while avoiding the pollution of the product surface by the traditional silicone oil system.
Complex structural products: such as car seat foam, its excellent leveling properties can ensure uniform coverage of the corners of the mold cavity and avoid tearing of the product due to insufficient local release force.
3. Performance breakthrough direction: material design and process optimization
Molecular structure customization
By adjusting the M/Q ratio (0.5-1.0) or introducing functional groups (such as vinyl and hydrogen groups), the crosslinking density, flexibility and reactivity of the resin can be accurately regulated to meet the needs of different composite material systems.
For example, methyl vinyl MQ silicone resin (model AM-8018) significantly improves the transparency and mechanical strength of silicone rubber by introducing vinyl, which is suitable for the field of optical grade packaging.
Synergy of composite system
When combined with PDMS, epoxy resin and other matrix materials, MQ resin uses the dual effects of chemical bonding and physical filling to build a “rigid and soft” interface layer, balancing the strength and toughness of the material.
In high-temperature coatings, MQ resin and inorganic fillers (such as fumed silica) work synergistically to form a dense protective layer and improve the corrosion resistance and weather resistance of the coating.
Environmental protection and sustainability
MQ resin is prepared from methyl trichlorosilane, an industrial byproduct, as raw material to realize the resource reuse of waste materials, which is in line with the development trend of green chemistry.
The characteristics of low volatile content (<0.35%) and low impurity content (<50ppm) meet the stringent requirements for material cleanliness in electronics, medical and other fields.